In simple terms
A friendly intro before the formal notes — no formulas yet.
The Chemist's Counting Unit
The mole is a unit for counting a huge number of particles, like atoms or molecules. It allows us to connect the microscopic world of particles to the macroscopic world of mass and volume we can measure in the lab.
A baker doesn't count individual flour grains; they use a standard measure like a 'cup' or weigh it in grams. Similarly, chemists use the 'mole' as a standard amount to 'count' atoms, which are too small to see, simply by weighing them.
- 1
One mole contains Avogadro constant (6.02 × 10²³) particles.
- 2
n = m / Mr links mass to amount of substance.
- 3
Concentration c = n / V (mol dm^{-3}) for solutions.
- 4
Gas volume at rtp: .
Explore the concept
Use the live diagram and synced steps — play it or tap a step card to walk through.
Key formulas
Tap any symbol to reveal exactly what it means and its units.
Full topic notes
Formal explanation with the rigour you need for the exam.
The Mole and the Avogadro Constant
The mole (symbol: mol) is the SI unit for the amount of substance. It is formally defined based on a standard: one mole is the amount of substance containing as many elementary entities (e.g., atoms, molecules, ions, electrons) as there are atoms in exactly 12 grams of the carbon-12 isotope. This specific number of entities is known as the Avogadro constant.
1 mole contains particles.
This number, mol^{-1}, is the Avogadro constant ().
The particles can be atoms, molecules, formula units, or ions.
Number of particles = amount in moles () × Avogadro constant ()
Molar Mass: Linking Moles and Mass
The molar mass () of a substance is the mass of one mole of that substance. It is expressed in units of grams per mole (g mol^{-1}). Conveniently, the numerical value of the molar mass is the same as the relative atomic mass () for an element, or the relative molecular/formula mass () for a compound, which you can calculate using values from the Periodic Table.
Amount of substance () =
Concentration of Solutions
For reactions in solution, we use concentration to describe the amount of a solute dissolved in a certain volume of solvent. Concentration is defined as the amount of substance (in moles) per unit volume. The standard unit for volume in these calculations is the decimetre cubed (), which is equivalent to 1 litre.
Concentration () =
A very common mistake is forgetting to convert volumes given in to . Remember that . To convert from , you must divide by 1000. Always check your units before calculating!
The Molar Volume of Gases
Avogadro's Law states that equal volumes of different gases, at the same temperature and pressure, contain the same number of molecules (and therefore the same number of moles). This leads to the concept of molar volume. For A-Level Chemistry, you need to know that at room temperature and pressure (r.t.p. - approx. 25°C and 1 atm), one mole of any ideal gas has a volume of (or ).
Amount of gas () =
At r.t.p., this becomes: or
The molar volume of 24 .t.p. Do not use it for solids, liquids, or gases at other temperatures and pressures unless you are given a different value for the molar volume.
Worked examples
See the formulas applied — reveal one step at a time, like the exam.
Calculate the amount of substance (in moles) and the number of formula units in 25.0 g of calcium carbonate, CaCO₃. (Relative atomic masses: Ca = 40.1, C = 12.0, O = 16.0)
- 1
Calculate the molar mass () of CaCO₃:
A student dissolves 4.38 g of anhydrous sodium carbonate, Na₂CO₃, in water and makes the solution up to 250 . Calculate the concentration of the solution in mol dm^{-3}. (Relative atomic masses: Na = 23.0, C = 12.0, O = 16.0)
- 1
Calculate the molar mass () of Na₂CO₃:
How it all connects
The big idea sits in the middle — tap a linked idea to explore the link.
Tap a linked idea to see how it connects back to the main topic — that connection is what examiners reward.
Glossary
Try to recall each definition before you reveal it.
Quick check
Answer in your head first — then tap to check. No pressure.
Revision flashcards
Flip the card. Test yourself before the exam.
What is the definition of a mole?
The amount of substance that contains the same number of specified elementary entities as there are atoms in exactly 12 g of the carbon-12 isotope. This number is the Avogadro constant.
Key takeaways
Review these before you close the topic — retrieval beats re-reading.
- ✓
1 mole contains particles.
- ✓
This number, mol^{-1}, is the Avogadro constant ().
- ✓
The particles can be atoms, molecules, formula units, or ions.
- ✓
Number of particles = amount in moles () × Avogadro constant ()
Practice — then mark it
The whole point: a real Cambridge question, marked mark-by-mark.
Test your understanding
Test your understanding
Extra simulations & links
PhET, GeoGebra and other curated tools — open in a new tab.
Frequently asked
Checkpoint
One marked question is worth ten re-reads — close the loop before you move on.
Reading it isn’t knowing it — prove it.
Before you move on: do Test your understanding on paper, snap a photo, and get examiner-style feedback on exactly where you win and lose marks.