In simple terms
A friendly intro before the formal notes — no formulas yet.
Earth's Radiation Budget
Every warm object glows with thermal radiation, and how much it glows and at what wavelength depend only on its temperature. Earth sits in a balance: it soaks up short-wave sunlight and glows back long-wave infrared, and greenhouse gases tilt that balance by intercepting some of the outgoing infrared.
Think of a bank account whose balance must stay steady. Sunlight is the income, paid in as short-wave visible radiation. Earth's own infrared glow is the spending, paid out to space. If the account is to hold a constant balance, income must equal spending — and that fixed balance point is the planet's temperature. Greenhouse gases act like a partial withdrawal fee on the outgoing side: some infrared that tried to leave is intercepted and sent back, so to spend enough to stay balanced the surface must run hotter.
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A hot body radiates over a spread of wavelengths (a black-body spectrum); the hotter it is, the shorter its peak wavelength (Wien) and the greater its total power (Stefan–Boltzmann, ).
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The Sun (about 5800 K) peaks in the visible; the cooler Earth (about 255–288 K) peaks in the infrared.
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Earth absorbs incoming sunlight over its disc but radiates from its whole surface ; setting absorbed power equal to emitted power gives an equilibrium temperature.
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Greenhouse gases absorb outgoing infrared and re-emit it in all directions — some back down — reducing the net loss to space and raising the equilibrium surface temperature.
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Step 1
A hot body radiates over a spread of wavelengths (a black-body spectrum); the hotter it is, the shorter its peak wavelength (Wien) and the greater its total power (Stefan–Boltzmann, ).
Key formulas
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Full topic notes
Formal explanation with the rigour you need for the exam.
Black-body radiation and emission spectra
A black body is an idealised object that absorbs all radiation falling on it and, being the perfect absorber, is also the best possible emitter at any given temperature. Its emission spectrum — a graph of radiated intensity against wavelength — has a characteristic humped shape that depends only on temperature, not on what the body is made of. The Sun, stars and planets are all modelled as black bodies to good approximation. As a body gets hotter two things happen at once: the peak of the spectrum shifts to shorter wavelengths, and the area under the whole curve (the total power radiated) grows rapidly. Those two behaviours are captured by Wien's displacement law and the Stefan–Boltzmann law respectively.
A black body absorbs all incident radiation and is the ideal emitter; its spectrum depends only on temperature.
Peak shift (Wien): the hotter the body, the shorter the wavelength of maximum intensity.
Total power (Stefan–Boltzmann): the hotter the body, the greater the area under the spectrum, rising as .
The Sun (≈ 5800 K) peaks in the visible; the far cooler Earth peaks in the infrared — the key asymmetry behind the greenhouse effect.
Wien's displacement law
Wien's displacement law states that the wavelength at which the emission spectrum peaks is inversely proportional to the absolute temperature of the body.
where is the peak wavelength in metres, is the absolute temperature in kelvin, and m K is Wien's constant (data booklet). Because the relationship is inverse, doubling the temperature halves the peak wavelength. This law is what lets astronomers read a star's surface temperature straight off the colour of its light, and it is why a warming filament glows first dull red, then orange, then white as its peak marches from long to short wavelengths.
The Stefan–Boltzmann law, emissivity and albedo
The Stefan–Boltzmann law gives the total power radiated by a black body across all wavelengths. For a body of surface area at absolute temperature , the radiated power (often called luminosity for a star) is , with W m⁻² K⁻⁴. The fourth-power dependence is dramatic: doubling the temperature multiplies the power by . Real surfaces radiate a little less than a perfect black body, and this is accounted for by the emissivity (between 0 and 1), giving ; a perfect black body has . On the incoming side, not all sunlight reaching a planet is absorbed — the albedo is the fraction reflected straight back to space, so only a fraction is available to warm the planet. Keep the two ideas distinct: albedo governs reflection of incoming radiation, emissivity governs emission of outgoing radiation.
Stefan–Boltzmann: — total power radiated, with in KELVIN.
Emissivity (): real surface radiates ; black body has .
Albedo (): fraction of incoming radiation reflected; fraction is absorbed. Earth's average .
Albedo and emissivity are different quantities on opposite sides of the budget — do not confuse them.
The solar constant and the intensity received by a planet
The Sun's power spreads out over an ever-larger sphere as it travels, so the intensity (power per unit area) falls off as the inverse square of distance: . Evaluated at Earth's orbital distance, this intensity is called the solar constant, W m⁻² — the power per square metre arriving at the top of the atmosphere on a surface facing the Sun. But a planet does not present its whole surface to this beam. It intercepts sunlight only over its cross-sectional disc of area (the shadow it casts), while it radiates its own infrared from its entire spherical surface . That mismatch — catch over a disc, emit over a sphere — introduces the crucial factor of 4 into the energy balance.
Planetary energy balance and equilibrium temperature
If a planet's average temperature is steady, it must be in radiative equilibrium: the power it absorbs from the Sun equals the power it radiates back to space. The power absorbed is the solar constant times the intercepting disc, reduced by the reflected fraction: . The power radiated, from the whole sphere, is . Setting , the cancels — so the equilibrium temperature does not depend on the planet's size, only on the incoming intensity, its albedo and its emissivity.
For a black-body Earth () this predicts about 255 K, some 33 K below the observed 288 K. The atmosphere makes up the difference, and that is the greenhouse effect.
The greenhouse mechanism
The atmosphere is largely transparent to incoming short-wave sunlight, which passes through and is absorbed at the surface. The warmed surface then radiates long-wave infrared (its Wien peak lies in the IR because it is cool). Greenhouse gases — chiefly water vapour (H₂O), carbon dioxide (CO₂), methane (CH₄) and nitrous oxide (N₂O) — absorb this outgoing infrared. An absorbed IR photon raises a molecule to a higher vibrational energy state; the excited molecule then re-emits infrared in a random direction, so a significant fraction is radiated back down towards the surface. This returned radiation reduces the net rate of energy loss to space, and the surface must settle at a higher temperature before incoming and outgoing power balance once more. The molecular requirement is that the vibration changes the molecule's electric dipole moment; symmetric diatomic molecules like N₂ and O₂ cannot do this and so are not greenhouse gases, which is why the bulk of the atmosphere is IR-transparent.
Short-wave in: atmosphere is transparent to incoming solar radiation, which is absorbed at the surface.
Long-wave out: the warmed surface emits infrared (its black-body peak is in the IR).
Absorb and re-emit: greenhouse gases absorb outgoing IR and re-emit it in all directions, some back to the surface.
Net effect: reduced energy loss to space raises the equilibrium surface temperature.
Molecular basis: absorption needs a vibration that changes the dipole moment — so N₂ and O₂ do not contribute.
Examiners specifically reject vague answers like 'greenhouse gases trap heat like a blanket'. To earn the marks you must name the mechanism: the surface emits INFRARED, greenhouse gases ABSORB that infrared and RE-EMIT it (including back towards the surface). Those verbs — absorb and re-emit infrared — are what the mark scheme is looking for.
The enhanced greenhouse effect
The natural greenhouse effect described above is essential: without it Earth would sit near −18°C and be largely frozen. The enhanced greenhouse effect is the additional warming caused by human activities that raise greenhouse-gas concentrations — principally CO₂ from burning fossil fuels and deforestation, along with extra methane from agriculture and fossil-fuel extraction. Adding greenhouse gases increases the absorption of outgoing infrared, shifting the energy balance so that the surface warms until balance is restored at a higher temperature. Because CO₂ persists in the atmosphere for centuries and, unlike water vapour, is not controlled by temperature, it is treated as the primary driver of recent climate change even though water vapour is more abundant. Be precise with the terminology: the greenhouse effect is natural and beneficial, while the enhanced greenhouse effect is the human-driven intensification behind global warming.
Keep 'natural' and 'enhanced' distinct in every answer — marks are awarded for using the terms correctly. The problem discussed in climate questions is the ENHANCED greenhouse effect; the plain greenhouse effect is the natural process that keeps the planet habitable.
Common mistakes examiners penalise
Getting Wien's law the wrong way round — , so a hotter body peaks at a SHORTER wavelength. Treating peak wavelength as increasing with temperature loses the mark.
Using °C in a (or Wien) calculation — the Stefan–Boltzmann and Wien laws demand ABSOLUTE temperature; always convert to kelvin first.
Saying albedo is absorbed — albedo is the fraction REFLECTED; the fraction absorbed is . Mixing these up flips the whole energy balance.
Dropping the factor of 4 — a planet absorbs over a disc but radiates over a sphere ; forgetting the 4 gives a temperature that is too high.
Describing the mechanism as 'trapping heat like a blanket' — you must state that the surface emits infrared and greenhouse gases absorb and re-emit it; a vague 'trapping' statement scores nothing.
Confusing the greenhouse effect with the ozone hole — the greenhouse effect is about infrared in the lower atmosphere; ozone depletion is about UV in the stratosphere. They are unrelated issues.
Blurring natural and enhanced — name which one you mean; the natural effect is essential, the enhanced effect is the human-caused problem.
Model answer — marked the way our engine marks it
B.2 mixes calculation with explanation, and the explanation marks are awarded analytically — each distinct valid physics point is worth one mark. Method marks (M) credit correct reasoning, answer marks (A) credit a correct conclusion, and error-carried-forward (ECF) means a wrong value early on does not cost you the marks that follow, provided your method is written down. Study how each mark below is tied to a specific, named idea rather than to loose phrasing.
Where this leads
The radiation laws in this topic reach well beyond climate. Wien's law and the Stefan–Boltzmann law are the tools for reading a star's temperature and luminosity in astrophysics; the inverse-square intensity relation reappears wherever power spreads from a source, from sound to gravitation. Master the energy-balance habit — absorbed power in over the disc, radiated power out over the sphere, set them equal — and you have a template that solves planetary-temperature problems for any world, atmosphere or none.
Worked examples
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The Sun's emission spectrum peaks at a wavelength of m, and the Sun's radius is m. (a) Estimate the Sun's surface temperature. (b) Hence estimate the Sun's luminosity, treating it as a black body. [5]
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(a) Surface temperature from Wien's law. Rearrange for : K. [M1: correct rearrangement; A1: 5800 K]
Model the Earth as a black body with no atmosphere. Using the solar constant W m⁻², albedo and W m⁻² K⁻⁴, calculate the equilibrium surface temperature and comment on the result. [4]
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Step 1 — power absorbed over the intercepting disc. A fraction of the incident beam is absorbed over the disc : . [M1: uses disc area and ]
Explain, in terms of radiation, how greenhouse gases raise the surface temperature of a planet, and state one consequence of increasing their concentration. [4]
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Model answer. The planet's warmed surface emits long-wave infrared radiation towards space. Greenhouse gases in the atmosphere absorb some of this outgoing infrared radiation, raising the gas molecules to higher vibrational energy states. The molecules then re-emit infrared radiation in all directions, so a fraction is returned back down towards the surface. This reduces the net rate at which the planet loses energy to space, so the surface reaches equilibrium at a higher temperature than it otherwise would. Increasing the concentration of greenhouse gases increases this absorption and back-radiation, so the equilibrium surface temperature rises further (an enhanced greenhouse effect leading to global warming).
How it all connects
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Glossary
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Revision flashcards
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Black body
An idealised object that absorbs all radiation incident on it and, at a given temperature, is also the best possible emitter. Its emission spectrum (intensity against wavelength) depends only on temperature.
Key takeaways
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A black body absorbs all incident radiation and is the ideal emitter; its spectrum depends only on temperature.
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Peak shift (Wien): the hotter the body, the shorter the wavelength of maximum intensity.
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Total power (Stefan–Boltzmann): the hotter the body, the greater the area under the spectrum, rising as .
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The Sun (≈ 5800 K) peaks in the visible; the far cooler Earth peaks in the infrared — the key asymmetry behind the greenhouse effect.
Practice — then mark it
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Get a Paper 2 question marked: explain the greenhouse mechanism and calculate an equilibrium temperature with full working
Get a Paper 2 question marked: explain the greenhouse mechanism and calculate an equilibrium temperature with full working
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