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9701 · 3.4

Covalent bonding and coordinate (dative covalent) bonding

Atoms form covalent bonds by sharing electrons to achieve a more stable arrangement, like a full outer shell. A coordinate bond is just a special type of covalent bond where one atom generously provides both electrons for the share.

Need to know

What you need to know

  • Describe a covalent bond as the strong electrostatic attraction between a shared pair of electrons and the nuclei of bonded atoms.
  • Draw 'dot-and-cross' diagrams to represent the valence electrons in simple covalent molecules, including those with multiple bonds.
  • Explain and represent coordinate (dative covalent) bonding, where one atom provides both electrons to a shared pair.
  • Understand the relationship between the number of shared electron pairs (bond order), bond length, and bond strength.

Explanation

The Ultimate Electron Sharing Agreement

  1. Covalent bonds form when atoms share electron pairs.
  2. Each covalent bond = one shared pair (single bond) or multiple pairs (double/triple).
  3. Dative covalent bonds: both electrons come from one atom (e.g. NH₄⁺).
  4. Lewis structures show all valence electrons — dots or crosses per atom.