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9701 · 4.2

Bonding and structure — practice questions

Practice and worked examples for 9701 Bonding and structure. Short previews only — attempt the full question in MarkScheme against the official scheme.

Worked example 1

Explain why magnesium is a good electrical conductor whereas sulfur is an electrical insulator. Both are in Period 3.

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Magnesium has a giant metallic structure. [1] It consists of a lattice of Mg2+Mg^{2+} ions surrounded by a sea of delocalised electrons. [1] These electrons are mobile and free to move throughout the structure to carry charge. [1]

Sulfur has a simple molecular structure, existing as S8S_8 rings. [1] While there are strong covalent bonds within the molecules, there are only weak van der Waals' forces between the molecules. [1] There are no mobile charge carriers (free electrons or ions) to conduct electricity. [1]

Worked example 2

Explain the difference in melting points for sodium chloride (801C801\,^\circ\text{C}), silicon dioxide (1710C1710\,^\circ\text{C}), and iodine (114C114\,^\circ\text{C}). In your answer, you should refer to the structure and bonding of each substance.

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Sodium Chloride (NaCl): Has a giant ionic lattice structure. [1] There are strong electrostatic forces of attraction between oppositely charged Na+Na^+ and ClCl^- ions. [1] A large amount of energy is required to overcome these forces, resulting in a high melting point. [1]

Silicon Dioxide (SiO2SiO_2): Has a giant covalent (macromolecular) structure. [1] Each silicon atom is covalently bonded to 4 oxygen atoms, and each oxygen to 2 silicon atoms. [1] A very large amount of energy is needed to break these numerous strong covalent bonds, resulting in a very high melting point. [1]

Iodine (I2I_2): Has a simple molecular structure. [1] Within the I2I_2 molecules, there are strong covalent bonds. However, between the molecules, there are only weak van der Waals' forces. [1] Only a small amount of energy is needed to overcome these weak intermolecular forces, resulting in a low melting point. [1]