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9701 · 7.2

Brønsted-Lowry theory of acids and bases

Acids and bases are defined by their ability to 'pass' a proton (a hydrogen ion, H⁺) between them. The acid is the proton donor, and the base is the proton acceptor.

Need to know

What you need to know

  • A conjugate acid-base pair consists of two species that differ by exactly one proton ($H^+$).
  • The acid has the proton; the conjugate base does not.
  • Every acid-base reaction involves two conjugate acid-base pairs.

Explanation

The Proton Pass

  1. Brønsted-Lowry: acids donate H⁺, bases accept H⁺. Identify the acid and base in the equilibrium and label the conjugate pairs.
  2. Strong acids ionise fully; weak acids establish an equilibrium. Compare the pH of a strong versus a weak acid at the same concentration.
  3. Ka measures weak acid strength; pKa = −log Ka. Observe how the equilibrium position relates to acid strength.
  4. pH = −log[H⁺]. Learn how to calculate the pH of strong acids and make approximations for weak acids by linking pH meter readings to [H⁺].