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9702 · 14.1

Thermal equilibrium — practice questions

Practice and worked examples for 9702 Thermal equilibrium. Short previews only — attempt the full question in MarkScheme against the official scheme.

Worked example 1

Calculate the total energy required to heat 0.50 kg of water from 20 °C to 100 °C and then completely boil it. \ (Given: Specific heat capacity of water = 4200 J kg⁻¹ K⁻¹, Specific latent heat of vaporisation of water = 2.26 × 10⁶ J kg⁻¹).

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  1. Energy to heat the water (Q₁): \ We use Q = mcΔT. \ Mass (m) = 0.50 kg \ Specific heat capacity (c) = 4200 J kg⁻¹ K⁻¹ \ Temperature change (ΔT) = 100 °C - 20 °C = 80 K (Note: A change of 80 °C is the same as 80 K). \ Q₁ = 0.50 kg × 4200 J kg⁻¹ K⁻¹ × 80 K = 168,000 J \ \ 2. Energy to boil the water (Q₂): \ We use Q = mL. \ Mass (m) = 0.50 kg \ Specific latent heat of vaporisation (Lᵥ) = 2.26 × 10⁶ J kg⁻¹ \ Q₂ = 0.50 kg × 2.26 × 10⁶ J kg⁻¹ = 1,130,000 J \ \ 3. Total energy (Q_total): \ Q_total = Q₁ + Q₂ \ Q_total = 168,000 J + 1,130,000 J = 1,298,000 J \ Therefore, the total energy required is approximately 1.30 × 10⁶ J (to 3 significant figures).

Worked example 2

A 0.20 kg block of copper at 95.0 °C is placed into 0.50 kg of water in a well-insulated container. The initial temperature of the water is 25.0 °C. Calculate the final temperature of the copper and water once thermal equilibrium is reached. (Specific heat capacity of copper = 385 J kg⁻¹ K⁻¹, Specific heat capacity of water = 4200 J kg⁻¹ K⁻¹).

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  1. Principle: Assuming the container is perfectly insulated, the heat energy lost by the hot copper block will be equal to the heat energy gained by the colder water. This is the principle of conservation of energy. \ HeatLost(Copper)=HeatGained(Water)Heat Lost (Copper) = Heat Gained (Water) \ \ 2. Formula: Let the final equilibrium temperature be TfT_f. \ mc×cc×(TinitialcTf)=mw×cw×(TfTinitialw)m_c \times c_c \times (T_initial_c - T_f) = m_w \times c_w \times (T_f - T_initial_w) \ \ 3. Substitution: \ 0.20×385×(95.0Tf)=0.50×4200×(Tf25.0)0.20 \times 385 \times (95.0 - T_f) = 0.50 \times 4200 \times (T_f - 25.0) \ Note: We can use °C here because we are dealing with temperature differences, and a change of 1°C is equal to a change of 1K. \ \ 4. Calculation: \ 77×(95.0Tf)=2100×(Tf25.0)77 \times (95.0 - T_f) = 2100 \times (T_f - 25.0) \ 731577Tf=2100Tf525007315 - 77T_f = 2100T_f - 52500 \ 7315+52500=2100Tf+77Tf7315 + 52500 = 2100T_f + 77T_f \ 59815=2177Tf59815 = 2177T_f \ Tf=59815/2177T_f = 59815 / 2177 \ Tf27.4758...°CT_f \approx 27.4758... °C \ \ 5. Final Answer: The final equilibrium temperature is 27.5 °C (to 3 significant figures).